SYNTHESIS OF SOME POLYACETYLENES

被引：18

作者：

GHOSE, BN

机构：

[1] Research & Development Laboratory, Reliance Silicones, (India) Limited, A-12/13 MIDC Industrial Estate, TTC, New Bombay, 400 613, Thane Belapur Road, P

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1994年 / 24卷 / 01期

关键词：

D O I：

10.1080/00945719408000092

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Twenty seven polyacetylenes having an aryl group in the chain have been synthesized using silylation as the protection of the terminal ethynyl group followed by oxidative coupling of the acetylenes and Cadiot-Chodkiewicz coupling reactions. The compounds have been characterized by their IR, NMR, UV and Mass spectral data.

引用

页码：29 / 52

页数：24

共 20 条

[1] BHOLMANN F, 1955, CHEM BER, V88, P1017
[2] Cadiot P., 1969, CHEM ACETYLENE, P597
[3] LIMITING BATTERY PERFORMANCE PARAMETERS FOR POLYACETYLENE
CHIEN, JCW
SCHLENOFF, JB
[J]. NATURE, 1984, 311 (5984) : 362 - 363
[4] DWAIN MW, 1974, Patent No. 3821153
[5] RATES OF BASE CLEAVAGE OF X.C6H4.[C=C]N.MET3 COMPOUNDS (N=2 AND 3, M=SI AND GE), AND THEIR SIGNIFICANCE FOR THEORIES OF SUBSTITUENT EFFECTS
EABORN, C
EASTMOND, R
WALTON, DRM
[J]. JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1971, (01): : 127 - &
[6] CLEAVAGE OF X.C6H4.(C=C)N.GEET3 COMPOUNDS BY AQUEOUS METHANOLIC PERCHLORIC ACID - A REMARKABLE CONSTANCY OF BALANCE OF INDUCTIVE AND RESONANCE EFFECTS OF SUBSTITUENTS IN REACTIONS INVOLVING CARBONIUM ION FORMATION
EABORN, C
EASTMOND, R
WALTON, DRM
[J]. JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC, 1970, (04): : 752 - &
[7] SILYLATION AS A PROTECTIVE METHOD FOR TERMINAL ALKYNES IN OXIDATIVE COUPLINGS - GENERAL SYNTHESIS OF PARENT POLYYNES - H(C=C)NH (N=4-10, 12)
EASTMOND, R
WALTON, DRM
JOHNSON, TR
[J]. TETRAHEDRON, 1972, 28 (17) : 4601 - &
[8] EASTMOND R, 1972, TETRAHEDRON, V28, P4891
[9] THE ELECTROCHEMICAL OXIDATION OF POLYACETYLENE AND ITS BATTERY APPLICATIONS
FARRINGTON, GC
SCROSATI, B
FRYDRYCH, D
DENUZZIO, J
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1984, 131 (01) : 7 - 12
[10] GARITO AF, 1982, LASER FOCUS WORLD, V18, P59

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