EXCESS THERMODYNAMIC PROPERTIES OF MIXTURES OF ALKYL BENZOATES WITH N-HEPTANE

被引:3
作者
BLANCO, AM
ORTEGA, J
机构
[1] Laboratorio de Termodinámica y Fisicoquimica, Escuela Superior de Ingenieros Industriales, Universidad de Las Palmas de Gran Canaria, Las Palmas de Gran Canaria
关键词
BINARY MIXTURES; N-HEPTANE; METHYL ESTERS; THERMODYNAMIC PROPERTIES; VISCOSITY;
D O I
10.1007/BF01563794
中图分类号
O414.1 [热力学];
学科分类号
摘要
The paper reports h(E) values at 298.15 K and upsilon(E) and deltaeta values at various temperatures for binary mixtures of propyl or butyl benzoate and n-heptane. The excess Gibbs energy of viscous flow, DELTAg*E, and the thermodynamic activation properties were calculated from these values. The results are compared with those for similar mixtures and interpreted on the basis of the characteristic dipole-dipole interactions of alkyl esters.
引用
收藏
页码:699 / 710
页数:12
相关论文
共 11 条
[1]   STUDIES ON DENSITIES AND VISCOSITIES OF BINARY-MIXTURES OF ALKYL BENZOATES IN N-HEPTANE [J].
BLANCO, AM ;
ORTEGA, J ;
GARCIA, B ;
LEAL, JM .
THERMOCHIMICA ACTA, 1993, 222 (01) :127-136
[2]  
BLANCO AM, 1989, THESIS LICENCIATURA
[3]  
DUSSART O, 1976, J CHIM PHYS, V73, P837
[4]  
EYRING H, 1991, IND ENG CHEM, V33, P837
[5]   DENSITIES AND VISCOSITIES OF MIXING FOR THE BINARY-SYSTEM OF METHYL BENZOATE WITH NORMAL-NONANE AT DIFFERENT TEMPERATURES [J].
GARCIA, B ;
MIRANDA, MJ ;
LEAL, JM ;
ORTEGA, J ;
MATOS, JS .
THERMOCHIMICA ACTA, 1991, 186 (02) :285-292
[6]   THERMODYNAMICS OF ESTER-CONTAINING MIXTURES - EXCESS ENTHALPIES AND EXCESS VOLUMES FOR ALKYL ACETATES AND ALKYL BENZOATES + ALKANES, + BENZENE, + TOLUENE, AND + ETHYLBENZENE [J].
GROLIER, JPE ;
BALLET, D ;
VIALLARD, A .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1974, 6 (09) :895-908
[7]   DETERMINATION AND ALGEBRAIC REPRESENTATION OF VOLUMES OF MIXING AT 298.15-K OF METHYL N-ALKANOATES (FROM ETHANOATE TO N-PENTADECANOATE) WITH N-PENTADECANE [J].
ORTEGA, J ;
ALCALDE, R .
FLUID PHASE EQUILIBRIA, 1992, 71 (1-2) :49-62
[8]   REVISION OF INTERACTION PARAMETERS FOR ESTIMATING THE ENTHALPIES OF MIXTURES OF BENZYL ETHANOATE PLUS N-ALKANES OR 1-CHLOROALKANES USING THE UNIFAC MODEL WITH PRESENTATION OF NEW EXPERIMENTAL-DATA [J].
ORTEGA, J ;
LEGIDO, JL .
FLUID PHASE EQUILIBRIA, 1993, 86 :251-273
[9]   THERMODYNAMIC PROPERTIES OF (A METHYL ESTER+AN N-ALKANE) .1. HM(E) AND VM(E) FOR (XCH3(CH2)U-1CO2CH3 (U=1 TO 6)+(1-X)CH3(CH2)6CH3) [J].
ORTEGA, J ;
GONZALEZ, E ;
MATOS, JS ;
LEGIDO, JL .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1992, 24 (01) :15-22
[10]   VISCOSITIES OF NONELECTROLYTE LIQUID-MIXTURES .2. BINARY-MIXTURES OF N-HEXANE WITH ALKANOATES AND BROMOALKANOATES [J].
OSWAL, SL ;
DAVE, JP .
INTERNATIONAL JOURNAL OF THERMOPHYSICS, 1992, 13 (06) :943-955