FORMATION OF AN ALKYLPEROXOIRON(III) COMPLEX DURING OXIDATIONS CATALYZED BY MU-OXODIIRON(III) COMPLEXES

被引：72

作者：

MENAGE, S

WILKINSON, EC

QUE, L

FONTECAVE, M

机构：

[1] UNIV GRENOBLE 1,LEDSS,URA 332,F-38052 GRENOBLE 09,FRANCE

[2] UNIV MINNESOTA,DEPT CHEM,MINNEAPOLIS,MN 55455

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 02期

关键词：

COMPLEXES WITH OXYGEN LIGANDS; ENZYME MODELS; IRON COMPOUNDS; OXIDATIONS;

D O I：

10.1002/anie.199502031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

UV/Vis, resonance Raman, and EPR spectroscopy served in characterizing the alkylperoxoiron(III) complex 2, an intermediate in the oxidation of alcohols R'OH with alkyl hydroperoxides ROOH catalyzed by μ‐oxo complex 1. The results discussed may provide insight for studies of monooxygenases. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：203 / 205

页数：3

共 15 条

[1] RAMAN-SPECTROSCOPIC EVIDENCE FOR SIDE-ON BINDING OF PEROXIDE ION TO FE-III(EDTA)
AHMAD, S
MCCALLUM, JD
SHIEMKE, AK
APPELMAN, EH
LOEHR, TM
SANDERSLOEHR, J
[J]. INORGANIC CHEMISTRY, 1988, 27 (13) : 2230 - 2233
[2] THE SELECTIVE FUNCTIONALIZATION OF SATURATED-HYDROCARBONS - GIF CHEMISTRY
BARTON, DHR
DOLLER, D
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1992, 25 (11) : 504 - 512
[3] BURGER RM, 1981, J BIOL CHEM, V256, P1636
[4] BIOMIMETIC OXIDATION STUDIES .5. MECHANISTIC ASPECTS OF ALKANE FUNCTIONALIZATION WITH FE,FE2O, AND FE4O2 COMPLEXES IN THE PRESENCE OF HYDROGEN-PEROXIDE
FISH, RH
KONINGS, MS
OBERHAUSEN, KJ
FONG, RH
YU, WM
CHRISTOU, G
VINCENT, JB
COGGIN, DK
BUCHANAN, RM
[J]. INORGANIC CHEMISTRY, 1991, 30 (15) : 3002 - 3006
[5] STEADY-STATE KINETIC-ANALYSIS OF SOLUBLE METHANE MONO-OXYGENASE FROM METHYLOCOCCUS-CAPSULATUS (BATH)
GREEN, J
DALTON, H
[J]. BIOCHEMICAL JOURNAL, 1986, 236 (01) : 155 - 162
[6] [FE(PMA)]N+ (N = 1, 2) - GOOD MODELS OF FE-BLEOMYCINS AND EXAMPLES OF MONONUCLEAR NONHEME IRON COMPLEXES WITH SIGNIFICANT O2-ACTIVATION CAPABILITIES
GUAJARDO, RJ
HUDSON, SE
BROWN, SJ
MASCHARAK, PK
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (18) : 7971 - 7977
[7] ALKANE FUNCTIONALIZATION AT NONHEME IRON CENTERS - STOICHIOMETRIC TRANSFER OF METAL-BOUND LIGANDS TO ALKANE
KOJIMA, T
LEISING, RA
YAN, SP
QUE, L
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (24) : 11328 - 11335
[8] NICKEL CATALYSIS OF OLEFIN EPOXIDATION
KOOLA, JD
KOCHI, JK
[J]. INORGANIC CHEMISTRY, 1987, 26 (06) : 908 - 916
[9] LEISING RA, 1993, J AM CHEM SOC, V115, P618
[10] LIMPSCOMB JD, IN PRESS ANN REV MIC

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