MECHANISM OF THE PLATINUM-PROMOTED CONVERSION OF CL2C=PR TO R-C-EQUIVALENT-TO-P, WHERE R=2,4,6-TRI-TERT-BUTYLPHENYL

被引：22

作者：

JUN, H ^{[1
]}

ANGELICI, RJ ^{[1
]}

机构：

[1] IOWA STATE UNIV SCI & TECHNOL,DEPT CHEM,AMES,IA 50011

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 11期

关键词：

D O I：

10.1021/om00035a003

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Cl2C=PR with Pt(PEt3)4 to give R-C=P and Pt(PEt3)2Cl2 proceeds through intermediates II and III. An X-ray diffraction study shows that the 2,4,6-tri-tert-butylphenyl ring in III is no longer aromatic. However, the aromaticity is restored when migration of the R group from the P to C is completed in forming the R-C=P product.

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页码：4265 / 4266

页数：2

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