STRONG BINDING OF PARAQUAT AND POLYMERIC PARAQUAT DERIVATIVES BY BASKET-SHAPED HOSTS

被引：29

作者：

SCHENNING, APHJ

DEBRUIN, B

ROWAN, AE

KOOIJMAN, H

SPEK, AL

NOLTE, RJM

机构：

[1] UNIV NIJMEGEN,NSR CTR,DEPT ORGAN CHEM,6525 ED NIJMEGEN,NETHERLANDS

[2] UNIV UTRECHT,BIJVOET CTR BIOMOLEC RES CRYSTAL & STRUCT CHEM,UTRECHT,NETHERLANDS

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 19期

关键词：

CROWN ETHERS; PARAQUAT; SUPRAMOLECULAR CHEMISTRY;

D O I：

10.1002/anie.199521321

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Exceptionally high binding constants Ka of up to 57000 M −1 have been determined for the binding of paraquat and polymeric paraquat derivatives 2 in the cavities of basket‐shaped host molecules 1. Host–guest complexations of this kind are of interest with respect to the modification of the physical properties of electroactive polymers, which are potential molecular switches. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2132 / 2134

页数：3

共 12 条

[1] COMPLEXATION OF PARAQUAT BY A BISPARAPHENYLENE-34-CROWN-10 DERIVATIVE
ALLWOOD, BL
SPENCER, N
SHAHRIARIZAVAREH, H
STODDART, JF
WILLIAMS, DJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (14) : 1064 - 1066
[2] MOLECULAR MECCANO .1. [2]ROTAXANES AND A [2]CATENANE MADE TO ORDER
ANELLI, PL
ASHTON, PR
BALLARDINI, R
BALZANI, V
DELGADO, M
GANDOLFI, MT
GOODNOW, TT
KAIFER, AE
PHILP, D
PIETRASZKIEWICZ, M
PRODI, L
REDDINGTON, MV
SLAWIN, AMZ
SPENCER, N
STODDART, JF
VICENT, C
WILLIAMS, DJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (01) : 193 - 218
[3] THE SELF-ASSEMBLY OF COMPLEXES WITH [2]PSEUDOROTAXANE SUPERSTRUCTURES
ASHTON, PR
PHILP, D
REDDINGTON, MV
SLAWIN, AMZ
SPENCER, N
STODDART, JF
WILLIAMS, DJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (23) : 1680 - 1683
[4] THERMOTROPIC LIQUID-CRYSTALLINE MAIN-CHAIN VIOLOGEN POLYMERS - HOMOPOLYMER OF 4,4'-BIPYRIDYL WITH DITOSYLATE OF TRANS-1,4-CYCLOHEXANEDIMETHANOL AND ITS COPOLYMERS WITH DITOSYLATE OF 1,8-OCTANEDIOL
BHOWMIK, PK
XU, WH
HAN, HS
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1994, 32 (16) : 3205 - 3209
[5] LYOTROPIC LIQUID-CRYSTALLINE MAIN-CHAIN VIOLOGEN POLYMERS
BHOWMIK, PK
HAN, HS
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1995, 33 (10) : 1745 - 1749
[6] HILDEBRAND JA, 1949, J AM CHEM SOC, V71, P2703
[7] HOST-GUEST COMPLEXATION .1. CONCEPT AND ILLUSTRATION
KYBA, EP
HELGESON, RC
MADAN, K
GOKEL, GW
TARNOWSKI, TL
MOORE, SS
CRAM, DJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (08) : 2564 - 2571
[8] NAGUMURA T, 1991, J CHEM SOC CHEM COMM, V72
[9] ELECTRODE-KINETICS OF THIN POLYMER COMPLEX FILMS COMPOSED OF POLY(ALKYLENEVIOLOGEN) AND POLY (PARA-STYRENESULFONIC ACID)
OHSAKA, T
NAKANISHI, M
HATOZAKI, O
OYAMA, N
[J]. ELECTROCHIMICA ACTA, 1990, 35 (01) : 63 - 64
[10] BINDING FEATURES OF MOLECULAR CLIPS DERIVED FROM DIPHENYLGLYCOLURIL
SIJBESMA, RP
KENTGENS, APM
LUTZ, ETG
VANDERMAAS, JH
NOLTE, RJM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (20) : 8999 - 9005

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