PALLADIUM(0)-CATALYZED REACTION OF PROPARGYLIC PHOSPHATES WITH SMI2 - A HIGHLY REGIOSELECTIVE ROUTE TO THE SYNTHESIS OF ALLENES AND ACETYLENES

被引：29

作者：

MIKAMI, K

YOSHIDA, A

MATSUMOTO, S

FENG, F

MATSUMOTO, Y

SUGINO, A

HANAMOTO, T

INANAGA, J

机构：

[1] TOKYO INST TECHNOL,DEPT CHEM TECHNOL,MEGURO KU,TOKYO 152,JAPAN

[2] KYUSHU UNIV,INST FUNDAMENTAL RES ORGAN CHEM,HIGASHI KU,FUKUOKA 812,JAPAN

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 06期

关键词：

D O I：

10.1016/0040-4039(94)02357-H

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A highly regioselective reaction of propargylic phosphates has been established by using SmI2 and a Pd(0) catalyst to give allenes and acetylenes in high isolated yields depending on the substrate used.

引用

页码：907 / 908

页数：2

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