POLY[[4-(N-TERT-BUTYL-N-HYDROXYAMINO)PHENYL]ACETYLENE] AND THE MAGNETIC PROPERTY OF ITS RADICAL DERIVATIVE

被引：40

作者：

NISHIDE, H

KANEKO, T

YOSHIOKA, N

AKIYAMA, H

IGARASHI, M

TSUCHIDA, E

机构：

[1] Department of Polymer Chemistry, Waseda University

[2] Advanced Research Laboratory, Hitachi Ltd., Hatoyama

来源：

MACROMOLECULES | 1993年 / 26卷 / 17期

关键词：

D O I：

10.1021/ma00069a023

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

[4-(N-tert-Butyl-N-hydroxyamino)phenyllacetylene (7) was synthesized and polymerized to yield a solvent-soluble polyacetylene: poly[[4-(N-tert-butyl-N-hydroxyamino)phenyl]acetylene] (8). Oxidation of the polymer gave its radical derivative: the ESR spectrum showed a broad signal only in the DELTAm(s) = +/-1 region, and magnetic measurement with a SQUID magnetometer revealed an antiferromagnetic through-space interaction.

引用

页码：4567 / 4571

页数：5

共 37 条

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