PHOTOADDITION OF FE2S2(CO)(6) TO C-60

被引：31

作者：

WESTMEYER, MD ^{[1
]}

GALLOWAY, CP ^{[1
]}

RAUCHFUSS, TB ^{[1
]}

机构：

[1] UNIV ILLINOIS,SCH CHEM SCI,URBANA,IL 61801

来源：

INORGANIC CHEMISTRY | 1994年 / 33卷 / 21期

关键词：

D O I：

10.1021/ic00099a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The photochemical reaction of C-60 and excess Fe2S2(CO)(6) produces C-60[S2Fe2(CO)(6)](n) (n = 1-3). Chromatographic workup of the reaction mixture afforded pure C60S2-Fe-2(CO)(6) in high yields. This species was characterized by C-13 NMR and IR spectroscopies, as well as mass spectrometry and cyclic voltammetry. These experiments suggest that a variety of M-S-fullerene compounds could be prepared by the additions of metal sulfides to fullerenes.

引用

页码：4615 / 4616

页数：2

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