BICYCLO[3.3.1]NONANE APPROACH TO TRIQUINANES - FORMAL SYNTHESIS OF (+/-)-DELTA-9(12)CAPNELLENE AND (+/-)-DELTA-9(12)CAPNELLENE-8-BETA-10-ALPHA-DIOL

被引：11

作者：

GAMBACORTA, A

FABRIZI, G

BOVICELLI, P

机构：

[1] Centro CNR, Studio per la Chimica delle Sostanze Organiche Naturali. Dipartimento di Chimica, Università La Sapienza

来源：

TETRAHEDRON | 1992年 / 48卷 / 21期

关键词：

D O I：

10.1016/S0040-4020(01)80453-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new synthetic strategy for natural triquinanes is presented as a model study. Stereospecific rearrangement of the ready accessible bicyclo[3.3.1] nonanic acetoxychloride 6 gave the cis-pentalanic hydroxyaldehyde 5, which has been converted into the ketone 4 already reported as a key intermediate in some syntheses of the title capnellenes.

引用

页码：4459 / 4464

页数：6

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