SOLID-STATE BATTERIES USING SILVER-BASED GLASSY MATERIALS

被引:12
作者
BASKARAN, N [1 ]
GOVINDARAJ, G [1 ]
NARAYANASAMY, A [1 ]
机构
[1] PONDICHERRY UNIV,RAMAN SCH PHYS,PONDICHERRY 605014,INDIA
关键词
ELECTROLYTES; SILVER SELENO MOLYBDATE; SOLID-STATE BATTERIES;
D O I
10.1016/0378-7753(95)02183-H
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new, fast ion-conducting, silver seleno molybdate (SSM), glassy electrolyte has been synthesized. Solid-state primary cells of the design anode/solid electrolyte/cathode have been fabricated with the highest conducting composition of the SSM glass as the solid electrolyte. The polarization and discharge characteristics of the cells are studied with different compositions of the cathode material. The effect of adding the solid electrolyte and tetraalkylammonium iodide (alkyl=methyl, butyl) to the cathode on the cell performance is investigated. The cell parameters are evaluated and the results are compared with a cell of the type Ag/AgI/(iodine+graphite) (I+C) that is fabricated using polycrystalline AgI as the solid electrolyte.
引用
收藏
页码:153 / 157
页数:5
相关论文
共 11 条
[1]  
Munshi, Owens, Superionic Solids and Solid Electrolytes, (1989)
[2]  
Julien, Mater. Sci. Eng., 6 B, (1990)
[3]  
Mansen, Effect Of Iodine Vapor On Silver Iodide, The Journal of Physical Chemistry, 60, (1956)
[4]  
Schiraldi, Chiodelli, Magistris, J. Appl. Electrochem., 6, (1976)
[5]  
Vincent, Prog. Solid State Chem., 17, (1987)
[6]  
Ribbes, Solid-State Microbatteries, (1990)
[7]  
Minami, Materials for Solid State Batteries, (1986)
[8]  
Ribbes, Derold, Solid-State Ionic Devices, (1988)
[9]  
Govindaraj, Baskaran, Shahi, Manoravi, Solid State Ionics, 75, (1995)
[10]  
Wagner, Proc. Int. Comm. Electrochem. Thermo Kinetics, 7, (1955)