BIS[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]-PLATINUM(II) IODIDE BIS(DEUTERIOCHLOROFORM) SOLVATE

被引：11

作者：

FERGUSON, G

LOUGH, AJ

MCALEES, AJ

MCCRINDLE, R

机构：

[1] Department of Chemistry and Biochemistry, University of Guelph, Guelph, N1G2W1, ON

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270192010217

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the [(Ph2PCH2)2]Pt2+ cation the Pt atom lies on a crystallographic inversion centre (and has necessarily planar coordination) with Pt-P = 2.3310(13) and 2.3250(14) angstrom and intra-ring P-Pt-P = 82.09(5)-degrees. The unique five-membered PtP2C2 ring has close to an envelope conformation. The iodide ion lies in a general position and is hydrogen bonded to the deuterium of the deuteriochloroform of solvation with I...C = 3.891(8), I...D = 2.96 angstrom and I...D-C = 166-degrees.

引用

页码：573 / 576

页数：4

共 7 条

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