A SIMPLE POLYHETEROTOPIC MOLECULAR RECEPTOR DERIVED FROM BISPYRAZOLYLMETHANE SHOWING NEGATIVE ALLOSTERIC COOPERATION OF ZN(II)

被引：11

作者：

RODRIGUEZUBIS, JC

JUANES, O

BRUNET, E

机构：

[1] Departamento de Química, C-1. Facultad, Ciencias. Universidad Autónoma de Madrid

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 08期

关键词：

D O I：

10.1016/0040-4039(94)88048-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The preparation of 1 as a model for negative allostery is described. Transport experiments (bulk liquid membrane) of alkyl di- and monoammonium cations in the presence or absence of ZnI2 in the receiving phase evidenced strong negative allosteric effects of the metal towards ammonium complexation.

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页码：1295 / 1298

页数：4

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