MULTIPLE-SCATTERING CALCULATIONS ON A SERIES OF M(H2O)(6)(2+) COMPLEXES WITH M=V TO CU

被引:13
作者
BRIOIS, V
LAGARDE, P
BROUDER, C
SAINCTAVIT, P
VERDAGUER, M
机构
[1] LPS, F-54596 VANDOEUVRE LES NANCY, FRANCE
[2] LMCP, UA09, F-75252 PARIS 05, FRANCE
[3] LCMT, F-75252 PARIS 05, FRANCE
来源
PHYSICA B | 1995年 / 208卷 / 1-4期
关键词
D O I
10.1016/0921-4526(94)00632-6
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The metal K-edge X-ray absorption spectra of a series of M (H2O)(6)(2+) complexes with M = V to Cu have been recorded in aqueous solution. After the white line, all spectra are characterized by a structure whose intensity depends on the absorbing metal. From multiple-scattering (MS) calculations, it has been shown that this structure is due to the collinear MS paths M --> O --> M --> O --> M. The influence of the metal is understood by the analysis of the p phase shifts of the scatterers.
引用
收藏
页码:51 / 52
页数:2
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