HIGHLY EFFICIENT METHOD FOR EPOXIDATION OF OLEFINS WITH MOLECULAR-OXYGEN AND ALDEHYDES CATALYZED BY NICKEL(II) COMPLEXES

被引：154

作者：

YAMADA, T

TAKAI, T

RHODE, O

MUKAIYAMA, T

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 01期

关键词：

D O I：

10.1246/cl.1991.1

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of a catalytic amount of a bis(1,3-diketonato) nickel (II) complex, trisubstituted and exo-terminal olefins or norbornene analogues are smoothly monooxygeneated into the corresponding expoxides in high to quantitative yields on treatment with aldehyde under an atmospheric pressure of oxygen at room temperature.

引用

页码：1 / 4

页数：4

共 6 条

[1] SYNTHETIC STUDIES ON AN ANTITUMOR ANTIBIOTIC, BLEOMYCIN .26. CHIRAL ENVIRONMENT AROUND THE METAL CENTER OBSERVED BY THE EPOXIDATION WITH THE IRON COMPLEXES OF BLEOMYCIN AND THE SYNTHETIC ANALOG
KAKU, Y
OTSUKA, M
OHNO, M
[J]. CHEMISTRY LETTERS, 1989, (04) : 611 - 614
[2] MARCHON JC, 1989, SYNTHESIS-STUTTGART, P389
[3] PHOTOCHEMICAL EPOXIDATION OF OLEFINS WITH MOLECULAR-OXYGEN ACTIVATED BY OXO(TETRA-P-TOLYLPORPHINATO)MOLYBDENUM(V)
MATSUDA, Y
KOSHIMA, H
NAKAMURA, K
MURAKAMI, Y
[J]. CHEMISTRY LETTERS, 1988, (04) : 625 - 628
[4] MUKIYAMA T, 1990, CHEM LETT, P1661
[5] EPOXIDATION OF OLEFINS WITH MOLECULAR-OXYGEN AND ALCOHOL CATALYZED BY BIS(2-ALKYL-1,3-DIKETONATO)OXOVANADIUM(IV)
TAKAI, T
YAMADA, T
MUKAIYAMA, T
[J]. CHEMISTRY LETTERS, 1990, (09) : 1657 - 1660
[6] CATALYSIS OF ALKENE OXIDATION BY NICKEL SALEN COMPLEXES USING NAOCL UNDER PHASE-TRANSFER CONDITIONS
YOON, H
BURROWS, CJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (12) : 4087 - 4089

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