STUDY OF THE MIXED-VALENCE NASICON - NAX(NBIVNBV)1-X/3CR2X/3(PO4)3

被引:6
作者
AOUSTIN, S
TILLEMENT, O
QUARTON, M
机构
[1] Laboratoire de Cristallochimie du Solide, CNRS-URA 1388, Université P. et M. Curie, 75252 Paris Cedex 05
关键词
PHOSPHATES; NASICON; NIOBIUM; ELECTRIC CONDUCTORS;
D O I
10.1016/0025-5408(92)90239-V
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
New materials with both electronic and ionic conductivity have been synthesized : Mixed Valence NASICON. In order to study them, the Na(x)(Nb(IV)Nb(V))1-x/3Cr2x/3(PO4)3 solid solution has been prepared in the 0 less-than-or-equal-to x less-than-or-equal-to 3 range. Ionic and electronic conductivity measurements have been performed and have allowed to show off correlations between electronic and ionic conductivities.
引用
收藏
页码:1015 / 1022
页数:8
相关论文
共 13 条
[1]   RELATION STRUCTURE FAST ION CONDUCTION IN THE NASICON SOLID-SOLUTION [J].
BOILOT, JP ;
COLLIN, G ;
COLOMBAN, P .
JOURNAL OF SOLID STATE CHEMISTRY, 1988, 73 (01) :160-171
[2]   ELECTRONEGATIVITIES OF THE ELEMENTS [J].
GORDY, W ;
THOMAS, WJO .
JOURNAL OF CHEMICAL PHYSICS, 1956, 24 (02) :439-444
[3]   CRYSTAL STRUCTURE OF NAME2 4(PO4)3 - ME4 =GE TI ZR [J].
HAGMAN, LO ;
KIERKEGA.P .
ACTA CHEMICA SCANDINAVICA, 1968, 22 (06) :1822-&
[4]   CRYSTAL-STRUCTURES AND CRYSTAL-CHEMISTRY IN SYSTEM NA1+XZR2SIXP3-XO12 [J].
HONG, HYP .
MATERIALS RESEARCH BULLETIN, 1976, 11 (02) :173-182
[5]   NEW COMPOUNDS FOR ISFETS [J].
KLEITZ, M ;
MILLIONBRODAZ, JF ;
FABRY, P .
SOLID STATE IONICS, 1987, 22 (04) :295-303
[6]   A MIXED-VALENCE NIOBIUM PHOSPHATE WITH AN EMPTY NASICON STRUCTURE - NB2(PO4)3 [J].
LECLAIRE, A ;
BOREL, MM ;
GRANDIN, A ;
RAVEAU, B .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1989, 45 :699-701
[7]   REVISED EFFECTIVE IONIC-RADII AND SYSTEMATIC STUDIES OF INTERATOMIC DISTANCES IN HALIDES AND CHALCOGENIDES [J].
SHANNON, RD .
ACTA CRYSTALLOGRAPHICA SECTION A, 1976, 32 (SEP1) :751-767
[8]  
TILEMENT O, 1991, SOLID STATE IONICS, V44, P299
[9]  
TILLEMENT O, 1992, THESIS U PARIS 6
[10]  
TILLEMENT O, 1991, SOLID STATE IONICS, V8