TRIS(N-BUTYL)PHOSPHINE, TRIS(TERT-BUTYL)PHOSPHINE AND TRIS(TRIMETHYL-SILYL)PHOSPHINE

被引：36

作者：

BRUCKMANN, J

KRUGER, C

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270194014356

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Single crystals of the title compounds, C12H27P (1), C12H27P (2), and C9H27PSi3 (3), were grown in capillaries at low temperature using zone-melting techniques [Brodalla, Mootz, Boese & Osswald (1985). J. Appl. Cryst. 18, 316-319]. The molecular and crystal structures of all three compounds were determined at 102 K. Compound (1) has a pseudo-mirror plane and C-P-C angles between 100.5 (1) and 102.7 (1)degrees. Compound (2) has a pseudosymmetric threefold rotation axis and C-P-C angles of 107.1 (1), 107.4 (1) and 107.8 (1)degrees. Isomorphous compound (3) has Si-P-Si angles between 105.8 (1) and 106.5 (1)degrees.

引用

页码：1152 / 1155

页数：4