ON THE WAY TO LIGATING OLIGOCYCLOPENTADIENYLS - SYNTHESIS AND PRELIMINARY REACTIONS OF THE 2 ISOMERIC TERCYCLOPENTADIENYLS AND THEIR TRANSITION-METAL COMPLEXES

被引：29

作者：

BOESE, R

MYRABO, RL

NEWMAN, DA

VOLLHARDT, KPC

机构：

[1] UNIV CALIF BERKELEY,DEPT CHEM,BERKELEY,CA 94720

[2] UNIV CALIF BERKELEY LAWRENCE BERKELEY LAB,DIV MAT & CHEM SCI,BERKELEY,CA 94720

[3] UNIV ESSEN GESAMTHSCH,INST ANORGAN CHEM,W-4300 ESSEN 1,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 05期

关键词：

D O I：

10.1002/anie.199005491

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Homo‐ and heterotrinuclear transition‐metal complexes of the two tercyclopentadienyl isomers have now become accessible via a generalizable synthetic strategy. The tricyclic ligands are prepared by coupling the fulvalene dianion with 3‐chloro‐2‐cyclopentenone. Such transition‐metal complexes—with or without M‐M bonds—permit intramolecular transfer of the ligands L between the various metal atoms. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：549 / 552

页数：4

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