FORMATION OF RADICALS AND CATALYTIC ACTIVITY OF PENTASIL-TYPE ZEOLITES IN UNSATURATED HYDROCARBON CONVERSIONS .1. RADICAL FORMATION UPON OLEFIN ADSORPTION

被引：23

作者：

SLINKIN, AA

KUCHEROV, AV

KONDRATYEV, DA

BONDARENKO, TN

RUBINSTEIN, AM

MINACHEV, KM

机构：

[1] USSR Acad of Sciences, Moscow, USSR, USSR Acad of Sciences, Moscow, USSR

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1986年 / 35卷 / 01期

关键词：

HYDROCARBONS; -; Synthesis; ZEOLITES;

D O I：

10.1016/0304-5102(86)85060-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The formation of radicals upon adsorption of linear (C//3H//6), branched (isobutylene, 2,4,4-trimethylpentene-1) and cyclic (cyclopentene) olefins on pentasil-type zeolites at minus 78 degree C and 20 degree C has been studied. It is shown that on pentasil the process of C//3H//6 oligomerization proceeds to a certain extent, even at minus 78 degree C. Similarities in the processes on pentasil and H-mordenite, as well as differences in the structure of radical particles due to channel shape and size, have been found.

引用

页码：97 / 105

页数：9

共 11 条

[1] ADSORPTION AND ACTIVATION OF ETHENE BY ZEOLITE-H-ZSM-5 [J].