BAKEROL - AN UNUSUAL NOR-ACORANE HEMIKETAL FROM CUPRESSUS-BAKERI FOLIAGE

被引：8

作者：

COOL, LG ^{[1
]}

KIM, YK ^{[1
]}

ZAVARIN, E ^{[1
]}

BALL, GE ^{[1
]}

机构：

[1] UNIV CALIF BERKELEY,COLL CHEM,BERKELEY,CA 94720

来源：

PHYTOCHEMISTRY | 1994年 / 36卷 / 05期

关键词：

CUPRESSUS BAKERI; CUPRESSACEAE; FOLIAGE; SESQUITERPENOIDS; BAKEROL; NOR-ACORANE HEMIKETAL;

D O I：

10.1016/S0031-9422(00)89652-1

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Foliage of Cupressus bakeri was found to contain several acorane-related sesquiterpenoids. One of these was bakerol, a new nor-acorane hemiketal with a 3,5,5,8-tetramethyldicyclopenta[b,c]furan carbon skeleton; about 3% of the keto tautomer (2,6-dimethyl-9-(1-hydroxy-1-methylethyl)-spiro[4,4]nonan-1-one) was observed. Bakerol is also present in a related cypress, C. neoadensis.

引用

页码：1283 / 1285

页数：3

共 4 条

[1]

KIM YK, 1994, PHYTOCHEMISTRY, V36, P961, DOI 10.1016/S0031-9422(00)90472-2

[2] CHEMICAL DIVERSITY IN CUPRESSUS-BAKERI JEPS .2. VARIABILITY OF FOLIAR MONOTERPENOIDS AND SESQUITERPENOIDS OF CUPRESSUS-BAKERI [J].