LASER PHOTOELECTRON-SPECTROSCOPY OF GAS-PHASE CHLOROBENZENE-H(5) AND CHLOROBENZENE-D(5)

被引：14

作者：

ASSELIN, P

GOUZERH, A

PIUZZI, F

DIMICOLI, I

机构：

[1] Service des Photons, Atomes et Molécules, CEA, Centre d'Etudes de Saclay, 91191 Gif Sur Yvette Cedex

来源：

CHEMICAL PHYSICS | 1993年 / 175卷 / 2-3期

关键词：

D O I：

10.1016/0301-0104(93)85167-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We present here the first application of a ''magnetic bottle'' photoelectron spectrometer associated with a laser ionization source for studying the vibrational spectroscopy of large molecular ions. The instrument combines good resolution, very high and constant collection efficiency of electrons with up to 2 meV kinetic energy and ease of use. Photoelectron spectra of chlorobenzene-h5 and chlorobenzene-d5, after one- or two-color, two-photon ionization via various vibrational levels of the first excited neutral state B-1(2), have been investigated. This has enabled the assignment of 15 vibrational frequencies of the B-2(1) chlorobenzene-h5 ion and one of its deuterated homologues. The vibrational state distribution of the generated ions has been determined very precisely providing new data for further spectroscopic studies.

引用

页码：387 / 398

页数：12

共 36 条

[1] NEW ASPECTS OF THE CHANNEL-3 PROBLEM IN BENZENE, AS REVEALED BY MULTIPHOTON IONIZATION PHOTOELECTRON-SPECTROSCOPY [J].