CRYSTAL AND MOLECULAR-STRUCTURE OF 1,12-DICARBOXY-1,12-DICARBA-CLOSO-DODECABORANE(12), C4H12B10O4

被引：9

作者：

CENTORE, R ^{[1
]}

CIAJOLO, MR ^{[1
]}

TUZI, A ^{[1
]}

KOMAROVA, LG ^{[1
]}

RUSANOV, AL ^{[1
]}

VASNEV, VA ^{[1
]}

机构：

[1] RUSSIAN ACAD SCI,INEOS,MOSCOW 117812,RUSSIA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270193011783

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The fivefold symmetry of the carborane cage is slightly distorted because of small differences between the basal B-B bond lengths. The C ... C diameter of the cage is ca 0.3 angstrom shorter than the diameters involving para-boron atoms. Molecules of the title compound are bonded along extended rows through hydrogen bonds between carboxylic groups. The rows are parallel to the -a+b-c axis. Molecules are repeated along the rows by inversion centres.

引用

页码：905 / 907

页数：3

共 11 条

[1] MOLECULAR STRUCTURES OF 1,2-,1,7-, AND 1,12-DICARBA-CLOSO-DODECABORANE(12), B10C2H12 [J].