SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF SM(C8H8)(2,4-C7H11).THF

被引：19

作者：

JIN, JH ^{[1
]}

JIN, SC ^{[1
]}

JIN, ZS ^{[1
]}

CHEN, WQ ^{[1
]}

机构：

[1] ACAD SINICA,CHANGCHUN INST APPL CHEM,CHANGCHUN 130022,PEOPLES R CHINA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 19期

关键词：

D O I：

10.1039/c39910001328

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

SmCl3 reacts with K2C8H8 to yield the complex Sm(C8H8)Cl.2thf, which reacts with K(2,4-C7H11) (2,4-C7H11 = 2,4-dimethylcyclopentadienyl) to form Sm(C8H8)(2,4-C7H11).thf; the X-ray crystal structure of Sm(C8H8)(2,4-C7H11).thf shows that the 2,4-dimethylcyclopentadienyl has a 'U' conformation.

引用

页码：1328 / 1329

页数：2

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