SYNTHESIS AND CHARACTERIZATION OF CROSSLINKED POLYMERS FOR BIOMEDICAL COMPOSITES

被引:21
作者
HAN, YK [1 ]
EDELMAN, PG [1 ]
HUANG, SJ [1 ]
机构
[1] UNIV CONNECTICUT,POLYMER SCI PROGRAM,IMS,BOX 136,STORRS,CT 06268
来源
JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY | 1988年 / A25卷 / 5-7期
关键词
Composite Materials--Medical Applications - Plastics Films--Hydrolysis - Polymers--Crosslinking;
D O I
10.1080/00222338808053402
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Three kinds of low molecular weight unsaturated polyesters containing carbon-carbon double bonds were synthesized by the reaction of poly-(Ε-caprolactone) diol or D,L-lactide and glycolic acid with maleic anhydride or fumaric acid. These functionalized polymers were thermally crosslinked in the presence of radical initiator to prepare the crosslinked polymers available as a matrix resin for biomedical composites. Hydrolysis of the crosslinked polyesters was investigated in buffer solution at 37°C.
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页码:847 / 869
页数:23
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