STEREOISOMERIC FLAVOR COMPOUNDS .54. 8-MERCAPTO-PARA-MENTHAN-3-ONE - OPTICALLY PURE STEREOISOMERS AND CHIROSPECIFIC ANALYSIS

被引：24

作者：

KOPKE, T ^{[1
]}

MOSANDL, A ^{[1
]}

机构：

[1] UNIV FRANKFURT,INST LEBENSMITTELCHEM,ROBERT MAYER STR 7-9,W-6000 FRANKFURT,GERMANY

来源：

ZEITSCHRIFT FUR LEBENSMITTEL-UNTERSUCHUNG UND-FORSCHUNG | 1992年 / 194卷 / 04期

关键词：

D O I：

10.1007/BF01193223

中图分类号：

TS2 [食品工业];

学科分类号：

0832 ;

摘要：

8-Mercapto-p-menthan-3-one, a powerful flavour impact compound of Buchu leaf oil and well appreciated in the composition of flavours and fragrances has been synthesized as pure diastereoisomers by addition of H2S to (R)- and (S)-pulegone to yield chromatography. Using capillary gas chromatography and heptakis-(2,3,6-tri-O-methyl)-beta-cyclodextrin as the chiral stationary phase, all the four stereoisomers have been chirospecifically analysed and the main sensoric properties are described.

引用

页码：372 / 376

页数：5

共 12 条

[1]

BAUER K, 1990, COMMON FRAGRANCE FLA, P139

[2] NATURALLY OCCURRING TERPENE DERIVATIVES .47. NEW SESQUITERPENE FROM TANACETUM-BALSAMITA L SSP BALSAMITOIDES (SCHULTZ BIP) GRIERSON [J].

BOHLMANN, F ;

ZDERO, C ;

SCHWARZ, H .

CHEMISCHE BERICHTE-RECUEIL, 1975, 108 (05) :1369-1372

[3]

BOHLMANN F, 1975, ORG MAGN RESONANCE, V7, P462

[4] CONVENIENT SYNTHESIS OF (S)-(-)-PULEGONE FROM (-)-CITRONELLOL [J].

COREY, EJ ;

ENSLEY, HE ;

SUGGS, JW .

JOURNAL OF ORGANIC CHEMISTRY, 1976, 41 (02) :380-381

[5] SOLVENT EFFECTS IN NUCLEAR MEGNETIC RESONANCE .6. CONFORMATIONS OF SUBSTITUTED CYCLOHEXANONES [J].

FETIZON, M ;

GORE, J ;

LASZLO, P ;

WAEGELL, B .

JOURNAL OF ORGANIC CHEMISTRY, 1966, 31 (12) :4047-&

[6]

JORD H, 1989, REAGENTIEN NACHWEI A, V1, P195

[7] DIE GEWINNUNG VON CYCLISCHEN KETONEN DURCH INTRAMOLEKULARE ACYLIERUNG ALIPHATISCHER TERPENSAUREN [J].

KUHN, W ;

SCHINZ, H .

HELVETICA CHIMICA ACTA, 1953, 36 (01) :161-170

[8]

LAMPARSKY D, 1971, Tetrahedron Letters, V36, P3323

[9]

NOWOTNY HP, 1989, HRC-J HIGH RES CHROM, V12, P383

[10]

SCHMALZ HG, 1986, UNVEROFFENTLICH PRIV

← 1 2 →