NITRATE REMOVAL USING SUPPORTED LIQUID MEMBRANES - TRANSPORT MECHANISM

被引:26
作者
NEPLENBROEK, AM [1 ]
BARGEMAN, D [1 ]
SMOLDERS, CA [1 ]
机构
[1] UNIV TWENTE,DEPT CHEM TECHNOL,POB 217,ENSCHEDE,NETHERLANDS
关键词
COUPLED; FACILITATED TRANSPORT; LIQUID MEMBRANES; SUPPORTED LIQUID MEMBRANES; LIQUID MEMBRANE STABILITY;
D O I
10.1016/0376-7388(92)80019-G
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A new method is developed for the removal of nitrate ions from water. Nitrate ions can be removed from water almost completely, with a mobile carrier, by counter-transport of chloride ions through a supported liquid membrane. The transport characteristics of this process, in which the water phases are flowing parallel to flat membranes, are described. The results show that depending on the experimental conditions the flux is determined by the diffusion of the carrier through the membrane or by the diffusion of the nitrate ions through a laminar water layer at the feed side. The selectivity of the membrane, which depends on the type of the organic solvent, determines the influence of the chloride concentration in the stripping phase on the membrane flux. Furthermore the effect of carrier concentration is investigated.
引用
收藏
页码:107 / 119
页数:13
相关论文
共 25 条
[1]  
AMAROSO P, 1983, J MEMBRANE SCI, V16, P259
[2]  
BABCOCK WC, 1978, PB293029
[3]  
Bird R B., 2007, TRANSPORT PHENOMENA
[4]   FACILITATED TRANSPORT VIA CARRIER - MEDIATED DIFFUSION IN MEMBRANES .2. MATHEMATICAL ASPECTS AND ANALYSES [J].
GODDARD, JD ;
SCHULTZ, JS ;
SUCHDEO, SR .
AICHE JOURNAL, 1974, 20 (04) :625-645
[5]   ANION-SELECTIVE ELECTRODE BASED ON OLEOPHILIC ANION-EXCHANGE RESIN MEMBRANE [J].
IMATO, T ;
JYO, A ;
ISHIBASHI, N .
ANALYTICAL CHEMISTRY, 1980, 52 (12) :1893-1896
[6]   MECHANISM OF CHLORIDE-ION TRANSPORT THROUGH DIAPHRAGM-TYPE LIQUID MEMBRANE [J].
KATAOKA, T ;
NISHIKI, T ;
TAMURA, Y ;
UEYAMA, K .
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1980, 13 (01) :35-40
[7]  
KEDEM O, 1986, INT SOLVENT EXTRACTI
[8]   DECONTAMINATION OF NITRATE POLLUTED WATER [J].
KREEVOY, MM ;
KOTCHEVAR, AT ;
AFTEN, CW .
SEPARATION SCIENCE AND TECHNOLOGY, 1987, 22 (2-3) :361-372
[9]  
LAUCH RP, 1984, PB84211036
[10]   METAL-ION SEPARATION AND CONCENTRATION WITH SUPPORTED LIQUID MEMBRANES [J].
LOIACONO, O ;
DRIOLI, E ;
MOLINARI, R .
JOURNAL OF MEMBRANE SCIENCE, 1986, 28 (02) :123-138