STEREOSELECTIVE SYNTHESIS OF ENEDIYNES AND ENYNES BY CONDENSATION OF ALDEHYDES WITH GAMMA-(TRIALKYLSILYL)ALLENYLBORANES

被引：20

作者：

WANG, KK ^{[1
]}

WANG, ZG ^{[1
]}

GU, YG ^{[1
]}

机构：

[1] W VIRGINIA UNIV,DEPT CHEM,MORGANTOWN,WV 26506

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 52期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(00)61341-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enediynes and enynes with high geometric purity were synthesized by treating acetylenic and simple aldehydes with gamma-(tert-butyldimethylsilyl)allenylborane 2a followed by the elimination step of the Peterson olefination reaction.

引用

页码：8391 / 8394

页数：4

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