CONCISE ALLENE SYNTHESIS FROM PROPARGYLIC ALCOHOLS BY HYDROSTANNATION AND DEOXYSTANNYLATION - A NEW ROUTE TO CHIRAL ALLENES

被引：57

作者：

KONOIKE, T

ARAKI, Y

机构：

[1] Shionogi Research Laboratories, Shionogi and Co., Ltd., Fukushima-ku, Osaka

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 35期

关键词：

D O I：

10.1016/S0040-4039(00)61198-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Propargylic alcohols were converted to allenes in a two-step one-pot process comprised of hydrostannation of propargylic alcohols and subsequent deoxystannylation. Chiral (S)-2,3-decadiene of high enantiomeric excess (ee) can be prepared in a similar way.

引用

页码：5093 / 5096

页数：4

共 16 条

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