STEREOCONTROLLED OXAZOLIDINONE FORMATION BY THE ADDITION OF 4,5-DISUBSTITUTED IMINODIOXOLANE TO OXIRANE VIA A SPIRO COMPOUND

被引：9

作者：

BABA, A

SEKI, K

MATSUDA, H

机构：

[1] Department of Chemistry, Osaka University

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 08期

关键词：

D O I：

10.1021/jo00008a021

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

4,5-Disubstituted 2-imino-1,3-dioxalanes readily add to oxiranes in the presence of AlCl3, furnishing 1,3-oxazolidin-2-ones in a stereospecific manner, where the configurations of oxiranes and iminodioxolanes are responsible for the configuration of products and the feasibility of the addition, respectively. A preliminary adduct, a spiro compound intermediate, is isolated, and its decomposition to oxazolidinone is demonstrated.

引用

页码：2684 / 2688

页数：5

共 33 条

[1]

BABA A, 1985, SYNTHESIS-STUTTGART, P1144

[2]

BABA A, IN PRESS J HETEROCYC

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