AEROBIC OXIDATION OF ALDEHYDES, KETONES, SULFIDES, ALCOHOLS AND ALKANES CATALYZED BY POLYMERIZABLE BETA-KETOESTERATE COMPLEXES OF IRON(III), NICKEL(II) AND COBALT(II)

被引：45

作者：

GIANNANDREA, R ^{[1
]}

MASTRORILLI, P ^{[1
]}

NOBILE, CF ^{[1
]}

SURANNA, GP ^{[1
]}

机构：

[1] POLITECN BARI,IST CHIM,MISO,CNR,CTR METODOL INNOVAT SINTESI ORGAN,I-70126 BARI,ITALY

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1994年 / 94卷 / 01期

关键词：

ALCOHOLS; ALDEHYDES; BAYER-VILLIGER REACTION; C-H BOND ACTIVATION; COBALT; IRON; BETA-KETOESTERATE COMPLEXES; KETONES; OXIDATION; SULFIDES;

D O I：

10.1016/0304-5102(94)87027-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The oxidation of aldehydes, ketones, sulfides, alcohols and alkanes is achieved by using a soluble beta-ketoesterate complex of iron(III), nickel(II) or cobalt (II) in the presence of a branched aldehyde and molecular oxygen (or air) at room temperature and atmospheric pressure (Mukaiyama's conditions).

引用

页码：27 / 36

页数：10

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