O-ATOM INSERTION INTO SI-H BONDS BY DIOXIRANES - A STEREOSPECIFIC AND DIRECT CONVERSION OF SILANES INTO SILANOLS

被引：84

作者：

ADAM, W ^{[1
]}

MELLO, R ^{[1
]}

CURCI, R ^{[1
]}

机构：

[1] UNIV BARI,CNR,CTR METODOL INNOVAT SINTESI ORGAN,DEPT CHEM,I-70126 BARI,ITALY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 08期

关键词：

D O I：

10.1002/anie.199008901

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of silanols 2 from the corresponding silanes 1 is especially easy, if the latter are allowed to react with dimethyl or methyl(trifluoromethyl)dioxirane (1–18 min reaction time, quantitative yields of enantiomerically pure product after removal of the solvent). The experimental data are consistent with an oxene mechanism (R1R3 = alkyl, aryl). (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：890 / 891

页数：2

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