CARBORANYLNITRENES

被引：16

作者：

BLANCH, RJ ^{[1
]}

BUSH, LC ^{[1
]}

JONES, M ^{[1
]}

机构：

[1] YALE UNIV,DEPT CHEM,NEW HAVEN,CT 06511

来源：

INORGANIC CHEMISTRY | 1994年 / 33卷 / 02期

关键词：

D O I：

10.1021/ic00080a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The EPR spectra of carbon- and boron-attached carboranylnitrenes are described. The zero-field splitting parameter \D/hc\ shows that there is little delocalization of the nonbonding electrons into the cage.

引用

页码：198 / 199

页数：2

共 22 条

[1] PHOTOCHEMICAL AND THERMAL REARRANGEMENT OF HEAVIER MAIN-GROUP ELEMENT AZIDES [J].

BERTRAND, G ;

MAJORAL, JP ;

BACEIREDO, A .

ACCOUNTS OF CHEMICAL RESEARCH, 1986, 19 (01) :17-23

[2] 3-ORTHO-CARBORANYLCARBENES - LINEAR, GROUND-STATE TRIPLETS [J].

BLANCH, RJ ;

LI, J ;

BUSH, LC ;

JONES, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (23) :9236-9237

[3]

BOYER JH, 1954, CHEM REV, V54, P541

[4] A SIMPLE ROUTE TO C-MONOSUBSTITUTED CARBORANE DERIVATIVES [J].

GOMEZ, FA ;

HAWTHORNE, MF .

JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (05) :1384-1390

[5]

Griess P., 1864, PHILOS T R SOC LONDO, V13, P377

[6]

Grushin V. V., 1982, IAN SSSR KH, P2633

[7]

GRUSHIN VV, 1982, DOKL AKAD NAUK SSSR+, V264, P868

[8] ORTHO-CARBORANYLCARBENE - A LARGELY LOCALIZED DIVALENT CARBON INTERMEDIATE [J].

HUTTON, RS ;

ROTH, HD ;

CHARI, S .

JOURNAL OF PHYSICAL CHEMISTRY, 1981, 85 (07) :753-754

[9] CHEMISTRY OF BORANES .26. INNER DIAZONIUM SALTS 1,10-B10H8 (N2) 2, -B10CL8(N2)2, AND -B10I8(N2)2 [J].

KNOTH, WH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (05) :935-&

[10]

LEFFLER JE, 1961, CHEM IND-LONDON, P512

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