A NEW HYDROTALCITE-LIKE COMPOUND CONTAINING V3+ IONS IN THE LAYERS

被引：39

作者：

RIVES, V

LABAJOS, FM

ULIBARRI, MA

MALET, P

机构：

[1] UNIV CORDOBA,FAC CIENCIAS,DEPT QUIM INORGAN & INGN QUIM,E-14004 CORDOBA,SPAIN

[2] UNIV SEVILLA,FAC QUIM,DEPT QUIM INORGAN,E-41012 SEVILLE,SPAIN

来源：

INORGANIC CHEMISTRY | 1993年 / 32卷 / 23期

关键词：

D O I：

10.1021/ic00075a008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of a new layered double hydroxide possessing the hydrotalcite structure and having Mg2+ and V3+ ions in the layers is described. The structure has been confirmed by X-ray diffraction and XANES and EXAFS spectroscopies. V3+ ions occupy octahedral sites in the brucite-like layers.

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页码：5000 / 5001

页数：2

相关论文

共 10 条

[1]

ALLMANN R, 1970, CHIMIA, V24, P99

[2] HYDROTALCITE-TYPE ANIONIC CLAYS: PREPARATION, PROPERTIES AND APPLICATIONS [J].

Cavani, F. ;

Trifiro, F. ;

Vaccari, A. .

CATALYSIS TODAY, 1991, 11 (02) :173-301

[3] STUDIES IN THE MICA GROUP - X-RAY DATA ON ROSCOELITE AND BARIUM-MUSCOVITE [J].

HEINRICH, EW ;

LEVINSON, AA .

AMERICAN JOURNAL OF SCIENCE, 1955, 253 (01) :39-43

[4]

Jones W., 1990, PILLARED LAYERED STR, P67

[5]

NEWNHAM RE, 1962, Z KRISTALLOGRAPHIE, V0117

[6] THERMAL-CHARACTERISTICS OF A SYNTHETIC HYDROTALCITE-LIKE MATERIAL [J].

PESIC, L ;

SALIPUROVIC, S ;

MARKOVIC, V ;

VUCELIC, D ;

KAGUNYA, W ;

JONES, W .

JOURNAL OF MATERIALS CHEMISTRY, 1992, 2 (10) :1069-1073

[7]

Shriver D.F., 1986, MANIPULATION AIR SEN

[8] ANIONIC CLAYS WITH VARIABLE VALENCE CATIONS - SYNTHESIS AND CHARACTERIZATION OF [CO1-XALX(OH)2](CO3)X/2.NH2O [J].

ULIBARRI, MA ;

FERNANDEZ, JM ;

LABAJOS, FM ;

RIVES, V .

CHEMISTRY OF MATERIALS, 1991, 3 (04) :626-630

[9] K-EDGE ABSORPTION-SPECTRA OF SELECTED VANADIUM COMPOUNDS [J].

WONG, J ;

LYTLE, FW ;

MESSMER, RP ;

MAYLOTTE, DH .

PHYSICAL REVIEW B, 1984, 30 (10) :5596-5610

[10] CHARACTERIZATION OF MAGNESIUM ALUMINUM DOUBLE HYDROXIDE PREPARED FROM ALKOXIDES AND ITS PRODUCTS OF THERMOLYSIS [J].

YAMAGUCHI, O ;

TAGUCHI, H ;

MIYATA, Y ;

YOSHINAKA, M ;

SHIMIZU, K .

POLYHEDRON, 1987, 6 (07) :1587-1592