FE-57 MOSSBAUER-SPECTROSCOPY OF THE FES CATHODE IN THE LI/FES BATTERY SYSTEM

被引：10

作者：

JONES, CHW

KOVACS, PE

SHARMA, RD

MCMILLAN, RS

机构：

[1] Department of Chemistry, Simon Fraser University, Burnaby

[2] National Research Council, Ottawa, Ont.

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 10期

关键词：

D O I：

10.1021/j100373a082

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The mechanism of discharge of the Li|LiAsF6-propylene carbonate|FeS battery system has been studied by 57Fe Mössbauer spectroscopy of the cathode. The only product identifiable in the cathode reduction appears to be iron, some of which is present as small particles that exhibit superparamagnetism. There is no evidence for macroscopic amounts of a lithiated intermediate. © 1990 American Chemical Society.

引用

页码：4325 / 4329

页数：5

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