DIACETONEGLUCOSE AS AUXILIARY GROUP FOR THE ASYMMETRIC HETERO-DIELS-ALDER REACTION WITH NITROSOALKENES

被引：53

作者：

ARNOLD, T ^{[1
]}

ORSCHEL, B ^{[1
]}

REISSIG, HU ^{[1
]}

机构：

[1] TH DARMSTADT,INST ORGAN CHEM,PETERSENSTR 22,W-6100 DARMSTADT,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 08期

关键词：

D O I：

10.1002/anie.199210331

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Even without complexation effects, sugar auxiliaries can be employed to achieve high asymmetric induction. This is borne out by the highly diastereoselective transformations providing preparatively useful dihydrooxazines 1. The compound 1, R = Ph, was converted into the primary amine 2 (ee > 80%). DAG = diacetoneglucose.

引用

页码：1033 / 1035

页数：3

共 36 条

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