HIGH-PRESSURE OXIDATION OF LIQUID FUELS FROM LOW TO HIGH-TEMPERATURE .3. N-DECANE

被引：50

作者：

DAGAUT, P

REUILLON, M

CATHONNET, M

机构：

[1] C.N.R.S. Laboratoire de Combustion et Systemes Reactifs, 45071, Orleans Cedex 2, 1C, Avenue de la Recherche Scientifique

来源：

COMBUSTION SCIENCE AND TECHNOLOGY | 1994年 / 103卷 / 1-6期

关键词：

D O I：

10.1080/00102209408907703

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The oxidation of n-decane in a high-pressure jet-stirred reactor (JSR) has been investigated experimentally in a wide range of conditions covering the low and high temperature oxidation regimes (550-1150K, 10 atm, phi=0.1 to 1.5). Reactants, intermediates and final. products have been measured providing a detailed picture of n-decane oxidation. Cyclic ethers resulting from the so-called lwo-temperature oxidation chemistry of n-decane were identified. The results are interpreted in terms of reaction mechanism. A detailed chemical kinetic modeling of the high-temperature oxidation of n-decane is used to assess the influence of low temperature chemistry in the intermediate temperature range.

引用

页码：349 / 359

页数：11

共 21 条

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