A 1ST EXAMPLE OF CATALYTIC YLIDE EPOXIDATION REACTION - FACILE SYNTHESIS OF VINYL EPOXIDES FROM ALDEHYDES CATALYZED BY DIISOBUTYL TELLURIDE

被引：32

作者：

ZHOU, ZL ^{[1
]}

SHI, LL ^{[1
]}

HUANG, YZ ^{[1
]}

机构：

[1] ACAD SINICA,SHANGHAI INST ORGAN CHEM,ORGANOMETALL CHEM LAB,345 LINGLING LU,SHANGHAI 200032,PEOPLES R CHINA

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 52期

关键词：

D O I：

10.1016/S0040-4039(00)97324-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of cesium carbonate, a variety of aldehydes can be epoxidized directly with allyl bromide at 50-degrees-C under solid-liquid phase transfer condition by use of a catalytic amount of diisobutyl telluride to afford vinyl epoxides in good yields with predominant cis stereoselectivity.

引用

页码：7657 / 7660

页数：4

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