EVALUATION OF ATOMIC FLUORESCENCE DETECTION LIMITS WITH AN INDUCTIVELY COUPLED PLASMA AS AN EXCITATION SOURCE AND ATOMIZATION CELL

被引:32
作者
LONG, GL [1 ]
WINEFORDNER, JD [1 ]
机构
[1] UNIV FLORIDA,DEPT CHEM,GAINESVILLE,FL 32611
关键词
PLASMAS;
D O I
10.1366/0003702844555179
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
The use of an inductively coupled plasma, ICP, as an excitation source for atomic fluorescence spectrometric, AFS, in a second ICP is re-examined. Improvements in the ICP-ICP-AFS setup have allowed the lowering of the limits of detection by one to two orders of magnitude below that of previous work. Also discussed is a new mode of operation for the atomization cell ICP. Through simple torch-position and flow-rate adjustments, a thin plasma, which extends 20 to 30 cm above the torch, can be produced. This plasma is referred to as the pencil plasma. 13 refs.
引用
收藏
页码:563 / 567
页数:5
相关论文
共 13 条
[11]   REDUCTION OF ELECTRONIC NOISE IN INDUCTIVELY COUPLED PLASMA ATOMIC EMISSION AND FLUORESCENCE SPECTROMETRIC MEASUREMENTS [J].
LONG, GL ;
VOIGTMAN, EG ;
KOSINSKI, MA ;
WINEFORDNER, JD .
ANALYTICAL CHEMISTRY, 1983, 55 (08) :1432-1434
[12]   LIMIT OF DETECTION [J].
LONG, GL ;
WINEFORDNER, JD .
ANALYTICAL CHEMISTRY, 1983, 55 (07) :A712-+
[13]  
OMENETTO N, 1979, ANAL CHEM, V55, P1521