SYNTHESIS OF NOVEL MONOMERIC ZINC-OXYGEN COMPOUNDS CONTAINING DIETHYLZINC AND PYROCATECHOL OR SALIGENIN MOIETIES

被引：7

作者：

KURAN, W

MAZANEK, E

机构：

[1] Faculty of Chemistry, Technical University (Politechnika), 00-662 Warszawa

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 384卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(90)87048-I

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of diethylzinc with dihydric phenols such as pyrocatechol and saligenin in a molar ratio of 1 1 yield zinc pyrocatecholate and ethylzinc 2-hydroxymethylphenoxide, whereas a molar ratio of 3 2 gives zinc bis(2-ethylzincoxyphenoxide) and zinc bis(2-ethylzincoxyphenylmethoxide), respectively. The latter ethylzinc-oxygen compounds, containing zinc diphenoxide - or zinc dimethoxide - units complexed internally by ethylzinc groups, form monomeric species in 1,4-dioxane. © 1990.

引用

页码：13 / 17

页数：5