TRANSFORMATION OF AN ETA-4-CYCLOOCTA-1,5-DIENE (COD) LIGAND INTO AN ETA-1-ALKENYL GROUP FROM REACTIONS OF ETA-5-C5H5RUH(COD) WITH DIPHOSPHINES - THE X-RAY STRUCTURAL DETERMINATION OF THE ORANGE AND YELLOW FORMS OF CPRU(1-SIGMA-C8H13)(PH2PCH2PPH2)

被引：12

作者：

LILES, DC ^{[1
]}

OOSTHUIZEN, HE ^{[1
]}

SHAVER, A ^{[1
]}

SINGLETON, E ^{[1
]}

WIEGE, MB ^{[1
]}

机构：

[1] CSIR,NATL CHEM RES LAB,PRETORIA 0001,SOUTH AFRICA

来源：

ORGANOMETALLICS | 1986年 / 5卷 / 03期

关键词：

D O I：

10.1021/om00134a035

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：591 / 593

页数：3

共 15 条

[1]

ALBERS M, UNPUB

[2] THE PREPARATION AND SOME REACTIONS OF CHLORO(ETA-4-CYCLOOCTA-1,5-DIENE)(ETA-5-CYCLOPENTADIENYL)-RUTHENIUM(II) - A VERSATILE, NEW SYNTHETIC PRECURSOR FOR CYCLOPENTADIENYLRUTHENIUM(II) CHEMISTRY [J].

ALBERS, MO ;

OOSTHUIZEN, HE ;

ROBINSON, DJ ;

SHAVER, A ;

SINGLETON, E .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 282 (03) :C49-C52

[3]

ALLEN AR, 1983, J CHEM SOC DA, P927

[4] FORMATION OF ETA-3-CYCLOOCTENYL COMPLEXES FROM HYDRIDE TRANSFER-REACTIONS IN HYDRIDO(CYCLOOCTA-1,5-DIENE)TRIS(LIGAND)RUTHENIUM(II) CATIONS - THE DOMINANT ROLE OF STERIC EFFECTS [J].

ASHWORTH, TV ;

CHALMERS, AA ;

MEINTJIES, E ;

OOSTHUIZEN, HE ;

SINGLETON, E .

ORGANOMETALLICS, 1984, 3 (10) :1485-1491

[5] CATIONIC RUTHENIUM(II) SYSTEMS .1. PREPARATION AND REACTIVITY OF DIENE(HYDRAZINE)RUTHENIUM(II) CATIONS, AND FORMATION OF AMINO-BONDED HYDRAZONE COMPLEXES [J].

ASHWORTH, TV ;

SINGLETON, E ;

HOUGH, JJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (19) :1809-1815

[6]

ASHWORTH TV, UNPUB

[7]

COOPER NJ, 1979, J CHEM SOC DA, P1122

[8] REACTION OF CYANOMETHYL COMPLEX (ETA-5-C5H5)RE(NO)(PPH3)(CH2CN) WITH NORMAL-BULI/TMEDA - GENERATION, STEREOSPECIFIC ALKYLATION, AND BASICITY OF A TRANSITION-METAL-SUBSTITUTED CARBANION [J].

CROCCO, GL ;

GLADYSZ, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (13) :4103-4104

[9] NEW HIGH-YIELD SYNTHESES OF RUTHENOCENE AND OSMOCENE AND THEIR DECAMETHYL DERIVATIVES - THE CRYSTAL-STRUCTURE OF [RU(ETA-5-C5ME5)2] [J].

LILES, DC ;

SHAVER, A ;

SINGLETON, E ;

WIEGE, MB .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 288 (02) :C33-C36

[10] TRANSITION-METAL CATALYSIS OF PERICYCLIC REACTIONS [J].

MANGO, FD .

COORDINATION CHEMISTRY REVIEWS, 1975, 15 (2-3) :109-205

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