REACTIONS OF (ETA-3-ALLYL)TETRACARBONYLIRON CATIONS WITH THE HIGHLY FUNCTIONALIZED COPPER REAGENTS RCU(CN)ZNI

被引：21

作者：

YEH, MCP

TAU, SI

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 01期

关键词：

D O I：

10.1039/c39920000013

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The addition of the highly functionalized copper reagents RCu(CN)Znl to (eta(3)-allyl)Fe(CO)4 cations occurs mainly at the unsubstituted allyl terminus to yield the functionalized isoprenyl derivatives; with substituents on both ends of the allyl, the regular isoprenyl adducts are isolated together with ketone products which are derived from nucleophilic additions to the carbon monoxide ligands.

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页码：13 / 15

页数：3

相关论文

共 14 条

[1]

DIETER JW, 1987, TETRAHEDRON LETT, V218, P5415

[2] PROTONATION REACTIONS OF TRICARBONYLDIENEIRON COMPLEXES - FORMATION OF TETRACARBONYLALLYLIRON CATIONS [J].

GIBSON, DH ;

VONNAHME, RL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (14) :5090-&

[3] SYNTHESIS AND REACTIVITY TOWARD ACYL CHLORIDES AND ENONES OF THE NEW HIGHLY FUNCTIONALIZED COPPER REAGENTS RCU(CN)ZNI [J].

KNOCHEL, P ;

YEH, MCP ;

BERK, SC ;

TALBERT, J .

JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (10) :2390-2392

[4] APPROACHES TO SELECTIVE ISOPRENOLOGATION VIA REACTIONS OF (ETA-3-ALLYL)FE(CO)4(+) WITH ALLYL NUCLEOPHILES [J].

LI, Z ;

NICHOLAS, KM .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 402 (01) :105-112

[5]

PEARSON AJ, 1975, TETRAHEDRON LETT, V16, P3617

[6] SCOPE OF ANION ADDITION TO (ETA-4-1,3-CYCLOHEXADIENE)TRICARBONYLIRON(0) [J].

SEMMELHACK, MF ;

HERNDON, JW .

ORGANOMETALLICS, 1983, 2 (03) :363-372

[7] NUCLEOPHILE ADDITION CARBONYLATION WITH ETA-4-DIENETRICARBONYLIRON(0) COMPLEXES [J].

SEMMELHACK, MF ;

HERNDON, JW ;

SPRINGER, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (08) :2497-2499

[8] CYCLOPENTANONES FROM NUCLEOPHILIC-ADDITION CARBONYLATION TO (ETA-4-DIENE)FE(CO)3 COMPLEXES [J].

SEMMELHACK, MF ;

HERNDON, JW ;

LIU, JK .

ORGANOMETALLICS, 1983, 2 (12) :1885-1888

[9] IRON-PROMOTED ALLYLIC ALKYLATION - REGIOCHEMICAL, STEREOCHEMICAL, AND MECHANISTIC ASPECTS [J].

SILVERMAN, GS ;

STRICKLAND, S ;

NICHOLAS, KM .

ORGANOMETALLICS, 1986, 5 (10) :2117-2124

[10] NUCLEOPHILIC-ADDITION TO IRON TRICARBONYL COMPLEXES OF ALPHA,BETA-UNSATURATED KETONES [J].

THOMAS, SE .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (04) :226-227