CONTROL OF PRODUCT SELECTIVITY FOR THE EPOXIDATION OF ALLYL ALCOHOL BY VARIATION OF THE ACIDITY OF THE CATALYST TS-1

被引：43

作者：

HUTCHINGS, GJ

LEE, DF

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 09期

关键词：

D O I：

10.1039/c39940001095

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The acidity of TS-1 controls the product selectivity for the epoxidation of allyl alcohol with H2O2; base treatment of TS-l enhances the selectivity to glycidol whereas incorporation of Bronsted acid sites enhances the selectivity to the products of solvolysis ring opening reactions.

引用

页码：1095 / 1096

页数：2

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