[CU44SE22(PET(2)PH)(18)] AND [CU44SE22(PNBUTBU(2))(12)] - SYNTHESIS AND STRUCTURE OF 2 COPPER CLUSTERS WITH ISOMERIC CU-SE FRAMEWORKS

被引：34

作者：

DEHNEN, S ^{[1
]}

FENSKE, D ^{[1
]}

机构：

[1] UNIV KARLSRUHE,INST ANORGAN CHEM,D-76131 KARLSRUHE,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 22期

关键词：

D O I：

10.1002/anie.199422871

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of copper(I) acetate with Se(SiMe3)2 in the presence of tertiary phosphanes leads to the formation of clusters 1 and 2. The crystal structures of these two clusters show that the CuSe frameworks are isomers, whose structures differ considerably as a result of different ligand shells. The Se22 framework of 2 is shown on the right. (Formula Presented.) (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2287 / 2289

页数：3

共 9 条

[1] NEW SULFUR-BRIDGED AND SELENIUM-BRIDGED COPPER CLUSTERS - AB-INITIO CALCULATIONS ON [CU2NSEN(PH3)(M)] CLUSTERS
DEHNEN, S
SCHAFER, A
FENSKE, D
AHLRICHS, R
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (07): : 746 - 749
[2] Dehnen S, 1994, ANGEW CHEM, V106, P786
[3] NEW COPPER CLUSTERS CONTAINING SE AND PET3 AS LIGANDS - [CU70SE35(PET3)22] AND [CU20SE13(PET3)12]
FENSKE, D
KRAUTSCHEID, H
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (12): : 1452 - 1454
[4] SYNTHESIS AND STRUCTURE OF NOVEL CU-CLUSTERS - [CU30-XSE15(PIPR3)12] (X = 0,1) AND [CU36SE18(PTBU3)12]
FENSKE, D
KRAUTSCHEID, H
BALTER, S
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (07): : 796 - 799
[5] FENSKE D, 1990, ANGEW CHEM, V102, P799
[6] FENSKE D, 1990, ANGEW CHEM INT EDIT, V102, P1513
[7] KRAUTSCHEID H, 1993, ANGEW CHEM INT EDIT, V32, P1303, DOI 10.1002/anie.199313031
[8] KRAUTSCHEID H, 1993, ANGEW CHEM, V105, P1364
[9] TOLMAN CA, 1977, CHEM REV, V77, P131

← 1 →