TRICHLOROTIN(II)-(MESO-TETRAPHENYLPORPHYRINATO)RHODIUM(III), A PORPHYRIN DERIVATIVE WITH AN RH-SN BOND

被引：12

作者：

LICOCCIA, S ^{[1
]}

PAOLESSE, R ^{[1
]}

BOSCHI, T ^{[1
]}

BANDOLI, G ^{[1
]}

DOLMELLA, A ^{[1
]}

机构：

[1] UNIV PADUA, DIPARTIMENTO SCI FARMACEUT, I-35131 PADUA, ITALY

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270194012424

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of the title compound, trichloro-2 kappa(3)Cl-(5,10,15,20-tetraphenylporphyrinato- 1 kappa(4)N(21,22,)(23,24))rhodium(III)tin(II)(Rh-Sn), [RhSnCl3(C44H28N4)], consists of well separated units in which the Rh atom is five-coordinate at the center of a square-pyramidal polyhedron with the Sn atom at the top. The macrocylic unit is planar with the Rh atom displaced by only 0.02 Angstrom from the ring plane. The Rh-Sn bond length is 2.450 (1) Angstrom.

引用

页码：833 / 835

页数：3

共 13 条

[1] COMPLEXATION OF TIN(II) CHLORIDE BY A NOVEL MACROCYCLE CONTAINING RHODIUM AND NITROGEN BINDING-SITES - THE PREPARATION AND X-RAY CRYSTAL-STRUCTURE OF RH2SN2(CO)2CL6[MU-2,6-BIS(DIPHENYLPHOSPHINO)PYRIDINE]2 [J].

BALCH, AL ;

HOPE, H ;

WOOD, FE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (24) :6936-6941

[2] SYNTHESIS AND CHARACTERIZATION OF NOVEL RHODIUM PORPHYRIN DERIVATIVES WITH A METAL METAL BOND [J].

BOSCHI, T ;

LICOCCIA, S ;

PAOLESSE, R ;

TAGLIATESTA, P .

INORGANICA CHIMICA ACTA, 1988, 145 (01) :19-20

[3] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE COMPLEX MER-[(RH(CNC8H9)3(SNCL3)(MU-SNCL2))2] [J].

BOTT, SG ;

MACHELL, JC ;

MINGOS, DMP ;

WATSON, MJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, :859-862

[4] SYNTHESIS, STRUCTURE AND BONDING OF [CL2SN(RH(PME3)3CL)2].THF, AN UNUSUAL SN-II-RH-I ADDUCT [J].

CHAN, DMT ;

MARDER, TB .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (03) :442-443

[5] BENZOYL(2,7,12,17-TETRAETHYL-3,8,13,18-TETRAMETHYL-21H,23H-PORPHINATO)RHODIUM(III) [J].

GRIGG, R ;

TROCHAGRIMSHAW, J ;

HENRICK, K .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (SEP) :2455-2458

[6] PORPHYRINS .29. CRYSTAL AND MOLECULAR-STRUCTURE AND LUMINESCENCE OF BIS(DIMETHYLAMINE)ETIO(I)PORPHINATORHODIUM(III) CHLORIDE DIHYDRATE [J].

HANSON, LK ;

GOUTERMAN, M ;

HANSON, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (15) :4822-4829

[7] NEUTRAL ETA-ARENE COMPLEXES OF RHODIUM(I) - X-RAY STRUCTURE OF ETA-TOLUENE(ETA-CYCLO-OCTENE)[BIS(BIS(TRIMETHYLSILYL)AMIDO)CHLOROSTANNATE(II)]RHODIUM(I) [J].

HAWKINS, SM ;

HITCHCOCK, PB ;

LAPPERT, MF .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (22) :1592-1593

[8]

HOLT MS, 1989, CHEM REV, V89, P101

[9]

JOHNSON CK, 1965, ORNL3794 REP

[10] METAL METAL BONDS EXTENDED OVER A PORPHYRIN RING .1. SYNTHESES OF (TPP)SN-M(CO)N-1-HG-M(CO)N AND (TPP)IN-M(CO)N (M(CO)N = MN(CO)5, CO(CO)4) AND X-RAY MOLECULAR-STRUCTURE ANALYSIS OF (TPP)SN-MN(CO)4-HG-MN(CO)5.1/2CH2CL2 [J].

ONAKA, S ;

KONDO, Y ;

YAMASHITA, M ;

TATEMATSU, Y ;

KATO, Y ;

GOTO, M ;

ITO, T .

INORGANIC CHEMISTRY, 1985, 24 (07) :1070-1076

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