SYNTHESIS OF NOVEL RIGID ROD IRON METAL CONTAINING POLYYNE POLYMERS

被引：72

作者：

JOHNSON, BFG ^{[1
]}

KAKKAR, AK ^{[1
]}

KHAN, MS ^{[1
]}

LEWIS, J ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,BIOCHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 409卷 / 03期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/0022-328X(91)80028-I

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of the dihaloiron-chelating phosphine complex, Fe(DEPE)2Cl2 (1) with 2.5 equivalents of Me3SnC=C6H5 (2) gives the monomeric complex, trans-Fe(DEPE)2(C=CC6H5)2 (3), whereas the reaction of equimolar quantities of 1 and Me3SnC=CRC=CSnMe3 (R = p-C6H4 (4); p-(CH3)2C6H2 (5)) yields soluble and high molecular weight rigid rod polymeric species, trans-[-Fe(DEPE)2(-C=CRC=C-)]n (6.7).

引用

页码：C12 / C14

页数：3

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