[INAS3]6- AND [ALSB3[6-, TRIGONAL PLANAR ANIONS IN CS6INAS3 AND CS6ALSB3

被引：4

作者：

BLASE, W

CORDIER, G

PETERS, K

SOMER, M

VONSCHNERING, HG

机构：

[1] MAX PLANCK INST FESTKORPERFORSCH,HEISENBERGSTR 1,W-7000 STUTTGART 80,GERMANY

[2] TH DARMSTADT,EDUARD ZINTL INST,W-6100 DARMSTADT,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 03期

关键词：

D O I：

10.1002/anie.199103261

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The anions of the complex salts Cs6InAs3 and Cs6AlSb3 are isosteric with borates. Both salts can be obtained as shiny metallic crystals directly from the elements. In the crystal the Cs atoms form a bundle of four chains of trigonal prisms which are centered by the atoms of the trigonal planar anions: proportional 1 {Cs12/2[MX3]}. The In As and Al-Sb bond lengths (261.5 and 263.7 pm, respectively) fall in the range typical for single bonds.

引用

页码：326 / 328

页数：3

共 15 条

[1] GAS-PHASE RAMAN SPECTROSCOPY OF TRIHALIDES OF ALUMINIUM, GALLIUM, AND INDIUM . RAMAN SPECTRA OF SOLID AND LIQUID INDIUM TRICHLORIDE AND TRIBROMIDE [J].