INSITU OBSERVATION OF THE PRESSURE-INDUCED AMORPHIZATION OF GEO2

被引:3
作者
KAWASAKI, S [1 ]
TAKUBO, H [1 ]
YAMANAKA, T [1 ]
机构
[1] OSAKA UNIV,COLL GEN EDUC,TOYONAKA,OSAKA 560,JAPAN
来源
PROCEEDINGS OF THE JAPAN ACADEMY SERIES B-PHYSICAL AND BIOLOGICAL SCIENCES | 1992年 / 68卷 / 09期
关键词
GEO2; AMORPHIZATION; HIGH PRESSURE;
D O I
10.2183/pjab.68.151
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
In order to study the stability field of GeO2 under high pressure at room temperature, an in situ observation was made by using a diamond anvil pressure cell, an optical microscope and a high speed VTR. At about 6.5 GPa, a transparent single-crystal of alpha-quartz type GeO2 quickly changed to a translucent material which was found to be X-ray amorphous. The loss of transparency induced by the transformation is attributed to the pulverization due to the large volume change (approximately 10%), which causes the increase of refractive index and introduces the imperfection into the single-crystal.
引用
收藏
页码:151 / 154
页数:4
相关论文
共 14 条
[1]  
FINCH CB, 1968, AM MINERAL, V53, P1394
[2]   PRESSURE MEASUREMENT MADE BY UTILIZATION OF RUBY SHARP-LINE LUMINESCENCE [J].
FORMAN, RA ;
BLOCK, S ;
BARNETT, JD ;
PIERMARINI, GJ .
SCIENCE, 1972, 176 (4032) :284-+
[3]   THE PRESSURE-INDUCED METALLIC AMORPHOUS STATE OF SNI4 .1. A NOVEL CRYSTAL-TO-AMORPHOUS TRANSITION STUDIED BY X-RAY-SCATTERING [J].
FUJII, Y ;
KOWAKA, M ;
ONODERA, A .
JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1985, 18 (04) :789-797
[4]   PRESSURE-INDUCED AMORPHIZATION OF CRYSTALLINE SILICA [J].
HEMLEY, RJ ;
JEPHCOAT, AP ;
MAO, HK ;
MING, LC ;
MANGHNANI, MH .
NATURE, 1988, 334 (6177) :52-54
[5]   PRESSURE-INDUCED COORDINATION CHANGES IN CRYSTALLINE AND VITREOUS GEO2 [J].
ITIE, JP ;
POLIAN, A ;
CALAS, G ;
PETIAU, J ;
FONTAINE, A ;
TOLENTINO, H .
PHYSICAL REVIEW LETTERS, 1989, 63 (04) :398-401
[6]  
KAWASAKI S, UNPUB
[7]   MEMORY GLASS - AN AMORPHOUS MATERIAL FORMED FROM ALPO4 [J].
KRUGER, MB ;
JEANLOZ, R .
SCIENCE, 1990, 249 (4969) :647-649
[8]   Germanium. XXXIX. The polymorphism of germanium dioxide [J].
Laubengayer, AW ;
Morton, DS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1932, 54 :2303-2320
[9]   MELTING ICE-I AT 77-K AND 10-KBAR - A NEW METHOD OF MAKING AMORPHOUS SOLIDS [J].
MISHIMA, O ;
CALVERT, LD ;
WHALLEY, E .
NATURE, 1984, 310 (5976) :393-395
[10]   HYDROSTATIC LIMITS IN LIQUIDS AND SOLIDS TO 100 KBAR [J].
PIERMARI.GJ ;
BLOCK, S ;
BARNETT, JD .
JOURNAL OF APPLIED PHYSICS, 1973, 44 (12) :5377-5382