THE FORMATION OF INTERCALATION COMPOUNDS OF MOS2 WITH CATIONS OF ALKALI-METALS AND ALKYLAMMONIUM FROM MONOLAYER DISPERSION OF MOLYBDENUM-DISULFIDE

被引:15
作者
GOLUB, AS
PROTSENKO, GA
GUMILEVA, LV
BUYANOVSKAYA, AG
NOVIKOV, YN
机构
[1] A.N.Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 117813
关键词
MOLYBDENUM DISULFIDE; INTERCALATION COMPOUNDS; ALKALI METAL CATIONS; ALKYLAMMONIUM HALIDES;
D O I
10.1007/BF00703994
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ion-exchange interaction of the monolayer aqueous dispersion obtained by hydration of crystalline LiMoS2 with Li, Na, K salts and alkylammonium halides is studied. Intercalation compounds of MoS2 with hydrated inorganic cations as well as hitherto unattainable intercalation compounds of MoS2 with alkylammonium cations are shown to be formed under these conditions. The composition and structure of these compounds are investigated.
引用
收藏
页码:632 / 634
页数:3
相关论文
共 4 条
[1]   INCLUSION SYSTEMS OF ORGANIC-MOLECULES IN RESTACKED SINGLE-LAYER MOLYBDENUM-DISULFIDE [J].
DIVIGALPITIYA, WMR ;
FRINDT, RF ;
MORRISON, SR .
SCIENCE, 1989, 246 (4928) :369-371
[2]   ELECTRONIC-PROPERTIES OF INTERCALATION COMPLEXES OF THE TRANSITION-METAL DICHALCOGENIDES [J].
FRIEND, RH ;
YOFFE, AD .
ADVANCES IN PHYSICS, 1987, 36 (01) :1-94
[3]  
SHOELHORN R, 1974, LESS COMM METALS, V36, P229
[4]   INCLUSION OF SUBSTITUTED FERROCENES AND AROMATIC-COMPOUNDS INTO MOS2 LAYERS AS NEW INTERCALATION COMPOUNDS [J].
TAGAYA, H ;
HASHIMOTO, T ;
KARASU, M ;
IZUMI, T ;
CHIBA, K .
CHEMISTRY LETTERS, 1991, (12) :2113-2116