ELECTROCHEMISTRY OF FULLERENE FILMS

被引：173

作者：

CHLISTUNOFF, J ^{[1
]}

CLIFFEL, D ^{[1
]}

BARD, AJ ^{[1
]}

机构：

[1] UNIV TEXAS,DEPT CHEM & BIOCHEM,AUSTIN,TX 78712

来源：

THIN SOLID FILMS | 1995年 / 257卷 / 02期

基金：

美国国家科学基金会;

关键词：

ELECTROCHEMISTRY; FULLERENES; INTERFACES; PHASE TRANSITIONS;

D O I：

10.1016/0040-6090(94)05703-6

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The preparation of C-60 films on electrodes by drop coating, Langmuir-Blodgett and electrochemical techniques, and the electrochemical behavior of these films in acetonitrile solutions containing a variety of supporting electrolytes (e.g., quaternary ammonium, alkali metal, and alkaline earth salts) is reviewed. Reduction can form insoluble films with incorporated cations or lead to dissolution. The large splitting between cathodic and anodic waves is discussed in terms of structural rearrangements during the redox processes. Studies of C-60 electrodes with the quartz crystal microbalance and with the scanning electrochemical microscope, and by laser-desorption mass spectrometry and surface-enhanced Raman scattering are also discussed.

引用

页码：166 / 184

页数：19

共 41 条

[1] HEAT-CAPACITY AND ORIENTATIONAL PHASE-TRANSITION OF SOLID C-60 PREPARED WITH DIFFERENT SOLVENTS [J].

ATAKE, T ;

TANAKA, T ;

KAWAJI, H ;

KIKUCHI, K ;

SAITO, K ;

SUZUKI, S ;

ACHIBA, Y ;

IKEMOTO, I .

CHEMICAL PHYSICS LETTERS, 1992, 196 (3-4) :321-324

[2]

Bard A. J., 1994, ELECTROANALYTICAL CH, V18, P243

[3]

Bard A. J., 2001, ELECTROCHEMICAL METH, V2nd, P50

[4] LANGMUIR-BLODGETT AND ELECTROCHEMICAL STUDIES OF FULLERENE FILMS [J].

BULHOES, LOS ;

OBENG, YS ;

BARD, AJ .

CHEMISTRY OF MATERIALS, 1993, 5 (01) :110-114

[5]

Buttry D.A., 1991, ELECTROANALYTICAL CH, V17, P1

[6] ELECTROCHEMICAL INTERCALATION OF LITHIUM INTO SOLID C60 [J].

CHABRE, Y ;

DJURADO, D ;

ARMAND, M ;

ROMANOW, WR ;

COUSTEL, N ;

MCCAULEY, JP ;

FISCHER, JE ;

SMITH, AB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (02) :764-766

[7]

CLIFFEL D, UNPUB

[8] VOLTAMMETRY AT C-60-MODIFIED ELECTRODES [J].

COMPTON, RG ;

SPACKMAN, RA ;

RILEY, DJ ;

WELLINGTON, RG ;

EKLUND, JC ;

FISHER, AC ;

GREEN, MLH ;

DOUTHWAITE, RE ;

STEPHENS, AHH ;

TURNER, J .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1993, 344 (1-2) :235-247

[9] A C-60 MODIFIED ELECTRODE - ELECTROCHEMICAL FORMATION OF TETRA-BUTYLAMMONIUM SALTS OF C-60 ANIONS [J].

COMPTON, RG ;

SPACKMAN, RA ;

WELLINGTON, RG ;

GREEN, MLH ;

TURNER, J .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1992, 327 (1-2) :337-341

[10] ELECTROCHEMICAL DETECTION OF FULLERONIUM AND HIGHLY REDUCED FULLERIDE (C-60(5-)) IONS IN SOLUTION [J].

DUBOIS, D ;

KADISH, KM ;

FLANAGAN, S ;

WILSON, LJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (20) :7773-7774

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