SYNTHESIS AND CONDUCTING PROPERTIES OF POLY[(DISILANYLENE)BUTENYNE-1,4-DIYLS) AND POLY[(DISILANYLENE)ETHYNYLENES]

被引：14

作者：

ISHIKAWA, M

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Hiroshima University, Higashi-Hiroshima

来源：

PURE AND APPLIED CHEMISTRY | 1991年 / 63卷 / 06期

关键词：

D O I：

10.1351/pac199163060851

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of 1,2-diethynyldisilanes with a catalytic amount of chlorotris (triphenylphosphine) rhodium(I) in toluene at room temperature afforded poly[(disilanylene)-butenyne-1,4-diyls]. Treatment of 1,2,5,6-tetrasilacyclo-octa-3,7-diyne with a catalytic amount of n-butyllithium THF at room temperature led to ring-opening polymerization to give poly[(disilanylene)ethynylenes]. When the films of poly[(disilanylene)butenyne-1,4-diyls] and poly[(disilanylene)ethynlyenes] were treated with antimony pentafluoride vapor, the highly conducting films were obtained.

引用

页码：851 / 854

页数：4

共 7 条

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[7] POLYMERIC ORGANO-SILICON SYSTEMS .5. SYNTHESIS OF POLY[(DISILANYLENE)BUTENYNE-1,4-DIYLS] WITH HIGHLY CONDUCTING PROPERTIES
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ISHIKAWA, M
YAMANAKA, T
[J]. ORGANOMETALLICS, 1989, 8 (08) : 2084 - 2085

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