SYNTHESIS OF MONOMERIC ORGANOSAMARIUM(III) CHALCOGENOLATES BY REDUCTIVE CLEAVAGE OF E-E BONDS (E=S, SE, TE)

被引：42

作者：

RECKNAGEL, A

NOLTEMEYER, M

STALKE, D

PIEPER, U

SCHMIDT, HG

EDELMANN, FT

机构：

[1] Institut für Anorganische Chemie der Universität Göttingen, W-3400 Göttingen

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 411卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)83040-B

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The THF adduct of decamethylsamarocene, Cp2*Sm(THF)2, reacts with disulfides, diselenides and ditellurides to give organosamarium(III) complexes containing a Sm-E bond (E = S, Se, Te). The molecular structures of the complexes Cp2*Sm(S2CNMe2) (1), Cp2*Sm[TeC6H2Me3-2,4,6](THF) (4) and Cp2*Sm[SeC6H2(CF3)3-2,4,6](THF) (5) have been determined by X-ray diffraction.

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页码：347 / 356

页数：10

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